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The analytical determinations are performed using mainly capillary electrophoresis, since it is a high-efficient, fast and cost-effective new separation method, which requires only a minute amount of sample for the analysis. The capillary electrophoresis has numerous advantages over the other separation techniques like HPLC, GC concerning the accessible maximum plate number, resolution, analysis time, cost of operation, consumption of reagents and chemicals, possibilities to automate. The capillary electrophoresis was proved to be useful for solving the different analytical problems of pharmaceutical and food industry, clinical and diagnostical investigations.